Having changed from windows 7 to windows 10 MS word now requires one to log into Microsoft Exchange to obtain address book MS exchange apparently is now required (at a PRICE) to send an E mails direct from MS word.
Which version of the Office Suite are you using.
When I use the Quick Access Toolbar in Word 2013 and select "Email" it automatically adds the document as an attachment and when I then click the email icon that is produced in Word 2013 it opens Outlook 2013 with the new document shown as an attachment.
Is your experience different?
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